A tris(mu-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue |
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| Authors: | Mirica Liviu M Stack T Daniel P |
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| Affiliation: | Department of Chemistry, Stanford University, Stanford, California 94305, USA. |
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| Abstract: | The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O2 yields a tris(mu-hydroxy)tricopper(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties. |
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