Recent advances in Gomberg-Backmann biaryl synthesis |
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Authors: | Toru Amaya Yuqing Jin Mamoru Tobisu |
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Affiliation: | Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan |
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Abstract: | The Gomberg-Bachmann reaction is an intermolecular aryl-aryl cross-coupling reaction using an arenediazonium salt and an arene. This digest review surveys recent advances in the Gomberg-Bachmann reaction. More specifically, it focuses on reaction systems that include 1) transition-metal-induced systems, 2) organic promoter-induced systems, 3) electrolytic systems, 4) photoreaction systems, and 5) hybrid systems consisted of a photoredox and a transition-metal catalyst. |
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Keywords: | Corresponding author. Gomberg-Bachmann reaction C-H arylation Homolytic aromatic substitution Radical chain reaction |
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