Photoreaction of anthracenyl phosphine oxides: Usual reversible photo- and heat-induced emission switching,and unusual oxidative PC bond cleavage |
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| Authors: | Kosuke Katagiri Yukina Yamamoto Yuui Takahata Ryoga Kishibe Naoki Fujimoto |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science and Engineering, Konan University, 8-9-1 Okamoto, Higashinada-ku, Kobe, Hyogo 658-8501, Japan;2. Graduate School of Natural Science, Konan University, 8-9-1 Okamoto, Higashinada-ku, Kobe, Hyogo 658-8501, Japan |
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| Abstract: | Anthracenyl(diphenyl)phosphine oxide and dianthracenylphenylphosphine oxide as photoactive compounds have been synthesized. Anthracenyl group of these compounds indicate the multi-functional roles such as an emission component, a photodimerization component, and a leaving group. When the light irradiation was performed under an oxygen atmosphere, photo-oxidative P | |
| Keywords: | Corresponding author. Phosphine oxide Photodimerization Anthracenyl group Oxidative cleavage |
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