| 一种含阻转异构体的二羧酸铀(Ⅵ)有机-金属配合物 |
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| 引用本文： | 瞿志荣.一种含阻转异构体的二羧酸铀(Ⅵ)有机-金属配合物[J].无机化学学报,2007,23(12):2126-2127. |
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| 作者姓名： | 瞿志荣 |
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| 作者单位： | 东南大学化学化工学院,南京,210096 |
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| 摘 要： | Uranium(Ⅵ) complex UO2((R，S)-1，1′-binaphthylene-2，2′-dicarboxylate)(H2O)] was obtained by the hydrothermal treatment of UO2(NO3)2·6H2O with (R，S)-1，1′-binaphthylene-2，2′-dicarboxylic acid(BCA) (L) in water at 180 ℃ in Pyrex tube. The crystal belongs to monoclinic system， space group C2/c， with a=1.640 3(3) nm， b=1.196 7(2) nm， c=1.066 3(17) nm， β=104.412(4)°， V=2.027 2(6) nm3， Z=4. CCDC: 659617.
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| 关 键 词： | 铀(Ⅵ)配合物 水热合成 晶体结构 |
| 文章编号： | 1O01-4861（2007）12-2126-02 |
| 收稿时间： | 2007-10-09 |
| 修稿时间： | 2007-11-22 |
Uranium(Ⅵ) Metal-organic Framework with Atropisomeric Dicarboxylic Ligand |
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| QU Zhi-Rong.Uranium(Ⅵ) Metal-organic Framework with Atropisomeric Dicarboxylic Ligand[J].Chinese Journal of Inorganic Chemistry,2007,23(12):2126-2127. |
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| Authors: | QU Zhi-Rong |
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| Abstract: | Uranium (Ⅵ) complex UO2((R,S)- 1,1' -binaphthylene-2,2'-dicarboxylate) (H2O)] was obtained by the hydrothermal treatment of UO2(NO3)2·6H2O with (R,S)-1,1'-binaphthylene-2,2'-dicarboxylic acid(BCA) (L) in water at 180 ℃ in Pyrex tube. The crystal belongs to monoclinic system, space group C2/c, with a=1.640 3(3) nm, b=1.1967(2) nm, c=1.066 3(17) nm, β=104.412(4)°, V=2.027 2(6) nm3, Z=4. CCDC: 659617. |
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| Keywords: | hydrothermal treatment crystal structure |
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