Solvent effects on the singlet - triplet equilibrium and reactivity of a ground triplet state arylalkyl carbene |
| |
| Authors: | Miguel A. Garcí a-Garibay, Craig Theroff, Steve H. Shin,Jesper Jernelius |
| |
| Affiliation: | Department of Chemistry and Biochemistry University of California, Los Angeles CA 90024 U.S.A. |
| |
| Abstract: | Results from intramolecular singlet and triplet specific reactivity in solvents of different Polarity suggest that the spin state equilibrium of 1,2-diphenyl-1-butylidene, a triplet ground state carbene. is largely susceptible to solvent polarity. The results are consistent with stabilization of the zwitterionic singlet state in solvents of high polarity. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
