| 一维链状锰配位聚合物[Mn(4-CPOA)(2，2-bipy)(H2O)]n的合成与晶体结构(英) |
| |
| 引用本文： | 高山,霍丽华,谷长生,赵辉,赵经贵.一维链状锰配位聚合物[Mn(4-CPOA)(2，2-bipy)(H2O)]n的合成与晶体结构(英)[J].无机化学学报,2005,21(9):1345-1348. |
| |
| 作者姓名： | 高山 霍丽华 谷长生 赵辉 赵经贵 |
| |
| 作者单位： | 黑龙江大学化学化工与材料学院，哈尔滨 150080,黑龙江大学化学化工与材料学院，哈尔滨 150080,黑龙江大学化学化工与材料学院，哈尔滨 150080,黑龙江大学化学化工与材料学院，哈尔滨 150080,黑龙江大学化学化工与材料学院，哈尔滨 150080 |
| |
| 基金项目： | 国家自然科学基金（No.20101003）和黑龙江省高校骨干教师基金（No.1054G036）资助项目. |
| |
| 摘 要： | A novel 1D coordination polymer of Mn(4-CPOA)(2,2-bipy)(H2O)]n (4-CPOA2-=4-carboxylphenoxyacetate) has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. The crystal crystallizes in monoclinic system, the space group is C2/c, with the crystal cell parameters a=1.437 9(2) nm, b=1.323 4(2) nm, c=1.970 5(3) nm, β=104.00(3)° and V=3.638 3(10) nm3, Mr=423.28, R=0.065 9, wR=0.130 3. The Mn(Ⅱ) ion displays a distorted octahedral coordination configuration, defined by three carboxyl O atoms from different 4-CPOA2- groups, two N atoms from the 2,2-bipyridine ligand and one water molecule. Adjacent Mn(Ⅱ) ions are linked by carboxylate groups into a chain structure with the Mn…Mn separation of 0.977 1(3) nm. The two-dimensional supramolecular network is constructed through intermolecular hydrogen bonds and π-π stacking interactions. CCDC: 224464.
|
| 关 键 词： | 锰配合物 4-羧基苯氧乙酸 晶体结构 |
| 文章编号： | 1001-4861(2005)09-1345-04 |
| 收稿时间： | 1/4/2005 12:00:00 AM |
| 修稿时间： | 2005-04-17 |
Synthesis and Crystal Structure of 1D Coordination Polymer [Mn(4-CPOA)(2,2-bipy)(H2O)]n with 4-Carboxylphenoxyacetate Ligand |
| |
| GAO Shan,HUO Li-Hu,GU Chang-Sheng,ZHAO Hui and ZHAO Jing-Gui.Synthesis and Crystal Structure of 1D Coordination Polymer [Mn(4-CPOA)(2,2-bipy)(H2O)]n with 4-Carboxylphenoxyacetate Ligand[J].Chinese Journal of Inorganic Chemistry,2005,21(9):1345-1348. |
| |
| Authors: | GAO Shan HUO Li-Hu GU Chang-Sheng ZHAO Hui and ZHAO Jing-Gui |
| |
| Institution: | School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080,School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080,School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080,School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 and School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 |
| |
| Abstract: | |
| |
| Keywords: | |
| 本文献已被 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
