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Capillarity creates single-crystal calcite nanowires from amorphous calcium carbonate
Authors:Kim Yi-Yeoun  Hetherington Nicola B J  Noel Elizabeth H  Kröger Roland  Charnock John M  Christenson Hugo K  Meldrum Fiona C
Affiliation:1. School of Chemistry, University of Leeds, Leeds, LS2?9JT (UK) http://www1.chem.leeds.ac.uk/FCM/;2. Department of Physics, University of York, York, YO10?5DD (UK);3. School of Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL (UK);4. School of Physics and Astronomy, University of Leeds, Leeds, LS2?9JT (UK)
Abstract:
Single-crystal calcite nanowires are formed by crystallization of morphologically equivalent amorphous calcium carbonate (ACC) particles within the pores of track etch membranes. The polyaspartic acid stabilized ACC is drawn into the membrane pores by capillary action, and the single-crystal nature of the nanowires is attributed to the limited contact of the intramembrane ACC particle with the bulk solution. The reaction environment then supports transformation to a single-crystal product.
Keywords:amorphous calcium carbonate  biomineralization  calcite  nanorods  nanowires
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