| 4,4-双十二烷基苯碘鎓六氟锑酸盐的制备 |
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| 引用本文： | 刘安昌,肖庆,温玉萍,谭珍友,刘芳.4,4-双十二烷基苯碘鎓六氟锑酸盐的制备[J].影像科学与光化学,2008,26(2):169-173. |
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| 作者姓名： | 刘安昌 肖庆 温玉萍 谭珍友 刘芳 |
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| 作者单位： | 武汉工程大学, 湖北省新型反应器与绿色化学工艺重点实际室, 湖北, 武汉, 430074 |
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| 基金项目： | 湖北省科技厅技术攻关项目 |
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| 摘 要： | 以十二烷基苯、碘酸钾为原料,醋酸酐为溶剂,在硫酸的作用下,制备了4,4-双十二烷基苯碘鎓盐酸盐.在环己烷溶液中,4,4-双十二烷基苯碘鎓盐酸盐与六氟锑酸钾进行离子交换得到目的产物4,4-双十二烷基苯碘鎓六氟锑酸盐.通过紫外光谱、红外光谱和核磁共振测定对产物进行了结构确证.
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| 关 键 词： | 碘鎓盐 十二烷基苯 六氟锑酸钾 |
| 收稿时间： | 2007-06-01 |
Study on the Preparation of Bisdodecylphenyliodonium Hexafluoroantimonate |
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| LIU An-chang,XIAO Qing,WEN Yu-ping,TAN Zhen-you,LIU Fang.Study on the Preparation of Bisdodecylphenyliodonium Hexafluoroantimonate[J].Imaging Science and Photochemistry,2008,26(2):169-173. |
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| Authors: | LIU An-chang XIAO Qing WEN Yu-ping TAN Zhen-you LIU Fang |
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| Institution: | Wuhan Institute of Technology, Hubei Key Lab of Novel Reactor & Green Chemical Technology, Wuhan 430074, Hubei, P.R.China |
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| Abstract: | Bisdodecylphenyliodonium hexafluoroantimonate salt was prepared via reaction of dodecyl benzene with KIO3 and H2SO4 in the presence of Ac2O to give the corresponding iodonium hydrogen sulfate, which was converted to the compound, via anion exchange with KSbF6. The structure of bisdodecylphenyliodonium hexafluoroantimonate salt was identified by UV, IR and H-NMR. |
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| Keywords: | iodonium salt doceyl benzene potassium hexafluoroantimonate |
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