| 1,1—二氰乙烯基—2,2—二硫醇盐第一过渡系列金属配合物的研究 Ⅱ.钒(Ⅳ)和铁(Ⅲ)配合物的研究 |
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| 引用本文： | 沈斐凤,耿志明,倪亚萍. 1,1—二氰乙烯基—2,2—二硫醇盐第一过渡系列金属配合物的研究 Ⅱ.钒(Ⅳ)和铁(Ⅲ)配合物的研究[J]. 无机化学学报, 1990, 0(3) |
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| 作者姓名： | 沈斐凤 耿志明 倪亚萍 |
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| 作者单位： | 杭州大学化学系，江苏省农业科学院食品饲料研究所，南京师范大学 杭州 310008，南京 210014南京大学 |
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| 摘 要： | 文献中研究了1,1-二氰乙烯基-2,2-二硫醇盐(简称i-mnt)的Cu(Ⅱ)和 Ni(Ⅱ)配合物.现合成出i-mnt的钒(Ⅳ)和铁(Ⅲ)配合物,根据钒(Ⅳ)配合物的ESR谱和铁(Ⅲ)配合物的Mossbauer谱及其他光谱探讨它们的键合和结构。
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| 关 键 词： | 2 2-二硫醇盐 钒(Ⅳ)配合物 铁(Ⅲ)配合物 |
RESEARCH ON THE FIRST-ROW METAL COMPLEXES CONTAINING 1,1-DICYANOETHYLENE-2,2-DITHIOLATE II.SYNTHESES AND SPECTRA OF Fe(III) AND V(IV) COMPLEXES |
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| Shen Feifeng. RESEARCH ON THE FIRST-ROW METAL COMPLEXES CONTAINING 1,1-DICYANOETHYLENE-2,2-DITHIOLATE II.SYNTHESES AND SPECTRA OF Fe(III) AND V(IV) COMPLEXES[J]. Chinese Journal of Inorganic Chemistry, 1990, 0(3) |
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| Authors: | Shen Feifeng |
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| Abstract: | Fe(III) and V(IV) coordination compounds containing 1,1-cyanoethylene-2,2-dithiolate (abbr. as i-mnt) were synthesized. They were characterized by elemental analyses, magnetic susceptibilities, infrared spectra and UV-spectra measurements. Fe(III) and V(IV) complexes were researched by Mossbauer spectrum and ESR spectrum respectively. The results indicated that Fe(III) complex is dimeric, and V(IV) complex is monomeric. |
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| Keywords: | 2 2-dithlolate vanadism(IV)eomplex Iron(III)complex |
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