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Prenylated isoflavones from Flemingia philippinensis
Authors:Li Hua  Yang Meihua  Miao Jianhua  Ma Xiaojun
Institution:Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100193, PR China.
Abstract:Two new prenylated isoflavones, named flemiphilippinins E and F, were isolated from the roots of Flemingia philippinensis, together with six known ones. The structures of the above compounds were established by spectroscopic methods. Flemiphilippinins E and F were identified as 5,4'-dihydroxy-8-(3,3-dimethylallyl)-6',6'-dimethyl-5'-(1,1-dimethylallyl) pyrano(2',3':7,6)isoflavone and 5,4'-dihydroxy-4',4',5'-trimethyl-4',5'-dihydrofurano(2',3':7,8) isoflavone, respectively, by a combination of HR-EI-MS, (1)H NMR, (13)C NMR, HMQC, HMBC, and NOESY spectra.
Keywords:NMR  1H NMR  13C NMR  2D NMR  prenylated isoflavones  Flemingia philippinensis
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