| V@CN催化的芳烃的氧气羟基化反应 |
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| 引用本文： | 李岩,李冰,陈婷,周志成,王军,黄军.V@CN催化的芳烃的氧气羟基化反应[J].催化学报,2015(7):1086-1092. |
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| 作者姓名： | 李岩 李冰 陈婷 周志成 王军 黄军 |
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| 作者单位： | 南京工业大学材料化学工程国家重点实验室,江苏南京,210009 |
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| 基金项目： | the National Natural Science of Foundation of China，the National High Technology Research and Develop-ment Program of China，the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD;38701001).基金来源:国家自然科学基金，国家高技术研究发展计划，江苏高校优势学科建设工程 |
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| 摘 要： | 制备了V@CN催化剂,并用于氧气条件下芳烃的直接羟基化反应。结果表明,在V@CN催化剂作用下,带有不同吸电子基团(CN, NO2, COOH, CF3和COCH3)的芳烃均可被O2氧化得到相应的酚,产率中等。含有卤素(F, Cl和Br)的芳烃也可在该催化体系作用下转化为相应的酚。
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| 关 键 词： | 羟基化 钒催化剂 芳烃 氧气 石墨相氮化碳 |
Direct hydroxylation of arenes with O2 catalyzed by V@CN catalyst |
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| Yan Li,Bing Li,Ting Chen,Zhicheng Zhou,Jun Wang,Jun Huang.Direct hydroxylation of arenes with O2 catalyzed by V@CN catalyst[J].Chinese Journal of Catalysis,2015(7):1086-1092. |
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| Authors: | Yan Li Bing Li Ting Chen Zhicheng Zhou Jun Wang Jun Huang |
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| Abstract: | A vanadium doped graphitic carbon nitride catalyst has been prepared and used for the direct hy-droxylation of arenes with O2. Substituted arenes with electron-withdrawing groups such as CN, NO2, COOH, CF3, and COCH3 were oxygenated to the corresponding phenols in moderate yields. The catalyst also proved applicable for the hydroxylation of aromatic halides (F, Cl, and Br) with O2. |
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| Keywords: | Hydroxylation Vanadium Arene Oxygen Graphitic carbon nitride |
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