| N-邻羟苄亚基苯胺Schiff碱铜配合物的合成、结构和性能表征(英) |
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| 引用本文： | 建方方,李 琳,孙萍萍,肖海连.N-邻羟苄亚基苯胺Schiff碱铜配合物的合成、结构和性能表征(英)[J].无机化学学报,2004,20(11):1295-1298. |
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| 作者姓名： | 建方方 李 琳 孙萍萍 肖海连 |
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| 作者单位： | 青岛科技大学新材料与功能配合物实验室,青岛,266042 |
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| 基金项目： | 山东省自然科学基金项目(No.Y2002B06) |
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| 摘 要： | The structure of the title compound has been determined by X-ray crystallography. Each copper atom is chelated by two N-salicylidene-aniline anion ligands with Cu-O and Cu-N distances of 0.187 6(3) and 0.200 1(4) nm, respectively. The central copper(Ⅱ) is four-coordinated and in distorted square-planar environment. The phenyl rings with salicylidene moieties form a dihedral angle of 65.40°. There are C-H…π supramolecular interactions in the crystal structure. The title compound is also examined by elemental analysis, FT-IR, UV spectra and TG-DSC analysis. CCDC: 222315.
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| 关 键 词： | Schiff碱 铜配合物 TG 晶体结构 |
Synthesis,Structure and Properties of Copper (Ⅱ) Complex with Schiff Base Ligand N-Salicylidene-aniline:[Cu(C13H10NO)2] |
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| JIAN Fang-Fang,LI Lin,SUN Ping-Ping and XIAO Hai-Lian.Synthesis,Structure and Properties of Copper (Ⅱ) Complex with Schiff Base Ligand N-Salicylidene-aniline:[Cu(C13H10NO)2][J].Chinese Journal of Inorganic Chemistry,2004,20(11):1295-1298. |
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| Authors: | JIAN Fang-Fang LI Lin SUN Ping-Ping and XIAO Hai-Lian |
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| Institution: | New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao 266042,New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao 266042,New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao 266042 and New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao 266042 |
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| Abstract: | The structure of the title compound has been determined by X-ray crystallography. Each copper atom is chelated by two N-salicylidene-aniline anion ligands with Cu-O and Cu-N distances of 0.187 6(3) and 0.200 1(4)nm, respectively. The central copper(Ⅱ) is four-coordinated and in distorted square-planar environment. The phenyl rings with salicylidene moieties form a dihedral angle of 65.40°. There are C-H…π supramolecular interactions in the crystal structure. The title compound is also examined by elemental analysis, FT-IR, UV spectra and TG-DSC analysis. |
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| Keywords: | Schiff base copper(Ⅱ) complex TG crystal structure |
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