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Labile supramolecular structures and their dynamics in associated liquids based on NMR data
Authors:G. V. Lagodzinskaya  N. G. Yunda  G. B. Manelis
Affiliation:(1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432 Chernogolovka, Moscow Region, Russian Federation
Abstract:
The results of experimental research into structuration of associated pure liquids and electrolyte solutions in these liquids by NMR spectroscopy are summarized. The influence of self-organization on the rate and relay mechanism of proton mobility, chemical kinetics, and thermodynamics is analyzed. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 577–601, April, 2006.
Keywords:associated liquids  hydrazines  mineral acids  electrolyte solutions  compositions and structures of labile supramolecular systems  kinetics and mechanism of proton exchange in liquids  disproportionation of perchloric acid  NMR spectroscopy
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