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Structural and property correlations of ethylen-α-olefin copolymers
Authors:Prof Dr G Bodor  H J Dalcolmo  O Schröter
Institution:1. Polymer Research Institute, Bundapest, Hungary
3. Leuna-Werke ?Walter Ulbricht“, Merseburg, G.D.R.
4. Pedag. Hochschule, Erfurt, G.D.R.
Abstract:Ethyleneagr-olefin copolymers differ from other polyethylenes in that:
there is no long chain branching;
short chain branching is determined by the comonomer unit;
the molecular mass distribution is sharp;
the side chain distribution on different molecules is broad;
the sequential distribution of branching is very broad along the molecular chains, which becauses a multi-peak lamella distribution, and a multi-peak melting heat.
With the help of a cross-fractionation method we interpreted the differences of the experimental data, according to the molecular mass fractionation and the branching received.
Keywords:Polyethylene  sidechainbranching  fractionation  x-ray  DSC  NMRinvestigations  structure-propertycorrelations
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