Structural and property correlations of ethylen-α-olefin copolymers |
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Authors: | Prof Dr G Bodor H J Dalcolmo O Schröter |
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Institution: | 1. Polymer Research Institute, Bundapest, Hungary 3. Leuna-Werke ?Walter Ulbricht“, Merseburg, G.D.R. 4. Pedag. Hochschule, Erfurt, G.D.R.
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Abstract: | Ethylene-olefin copolymers differ from other polyethylenes in that:- |
there is no long chain branching;
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short chain branching is determined by the comonomer unit;
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the molecular mass distribution is sharp;
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the side chain distribution on different molecules is broad;
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the sequential distribution of branching is very broad along the molecular chains, which becauses a multi-peak lamella distribution, and a multi-peak melting heat.
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With the help of a cross-fractionation method we interpreted the differences of the experimental data, according to the molecular mass fractionation and the branching received. |
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Keywords: | Polyethylene sidechainbranching fractionation x-ray DSC NMRinvestigations structure-propertycorrelations |
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