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Formation of Fe i –B pairs in silicon at high temperatures
Authors:H P Gunnlaugsson  K Bharuth-Ram  M Dietrich  M Fanciulli  H O U Fynbo  G Weyer
Institution:1. Institute of Physics and Astronomy, Aarhus University, Ny Munkegade, 8000, ?arhus C, Denmark
2. School of Physics, University of KwaZulu-Natal, Durban, 4041, South Africa
3. EP Division, CERN, CH-1211, Geneva, 23, Switzerland
4. Laboratorio Nazionale MDM-INFM, Via C. Olivetti 2, 20041, Agrate Brianza, Italy
Abstract:We report on the detection of Fe i –B pairs in heavily B doped silicon using 57Fe emission Mössbauer spectroscopy following implantation of radioactive 57Mn+ parent ions (T 1/2?=?1.5 min) at elevated temperatures >?850 K. The Fe i –B pairs are formed upon the dissociation of Fe i –V pairs during the lifetime of the Mössbauer state (T 1/2?=?100 ns). The resulting free interstitial Fei diffuses over sufficiently large distances during the lifetime of the Mössbauer state to encounter a substitutional B impurity atom, forming Fe i –B pairs, which are stable up to ~1,050 K on that time scale.
Keywords:Fe            i              B  p++ B doped silicon  M?ssbauer spectroscopy
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