Hg2+-sensing system based on structures of complexes |
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| Authors: | Ikeda Mari Matsu-ura Aya Kuwahara Shunsuke Lee Shim Sung Habata Yoichi |
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| Institution: | Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 261-0013, Japan. |
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| Abstract: | The first example of a new Hg(2+)-sensing system based on the structures of complexes is reported. The system uses a combination of a new chiral bidentate ligand and CD spectroscopy. Significant CD spectral changes are observed when Hg(2+) is added, whereas no CD spectral changes are observed in the cases of Li(+), Na(+), K(+), Mg(2+), Ca(2+), Mn(2+), Fe(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Rb(+), Ag(+), Cd(2+), La(3+), Gd(3+), and Pb(2+). |
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