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Conductometric titrations of organic bases with boron tribromide in aprotic solvents
Affiliation:1. Department of Earth Sciences, Faculty of Education and Integrated Arts & Sciences, Waseda University, 1-6-1 Nishiwaseda, Shinjuku-ku, Tokyo 169-8050, Japan;2. Earthquake Research Institute, University of Tokyo, 1-1-1, Yayoi, Bunkyo-ku, Tokyo 113-0032, Japan;3. National Research Institute for Earth Science and Disaster Prevention, 3-1, Tennodai, Tsukuba, Ibaraki 305-0006, Japan
Abstract:Conductance curves are presented for the reactions between organic bases and boron tribromide in the non-aqueous solvents, thionyl chloride, nitrobenzene and thiophosphoryl chloride. Interpretations of the data on the basis of the electronic theory are suggested. The reactions re stoichiometric and should find application in analytical chemistry.
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