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Effect of wet spinning parameters on the properties of novel cellulosic fibres
Authors:Marianna Vehviläinen  Taina Kamppuri  Monika Rom  Jaroslaw Janicki  Danuta Ciechańska  Stina Grönqvist  Matti Siika-Aho  Kristina Elg Christoffersson  Pertti Nousiainen
Institution:1.Fibre Materials Science,Tampere University of Technology,Tampere,Finland;2.Institute of Textile Engineering and Polymer Materials, Faculty of Materials and Environmental Sciences,University of Bielsko-Biala,Bielsko-Biala,Poland;3.Department of Fibres from Natural Polymers,Institute of Biopolymers and Chemical Fibres,?ód?,Poland;4.VTT Biotechnology,VTT Technical Research Centre of Finland,Espoo,Finland;5.Domsj? Fabriker Ab,?rnsk?ldsvik,Sweden
Abstract:Novel cellulose fibres (Biocelsol) were spun by traditional wet spinning technique from the alkaline solution prepared by dissolving enzyme treated pulp directly into aqueous sodium zincate (ZnO/NaOH). The spinning dope contained 6 wt.% of cellulose, 7.8 wt.% of sodium hydroxide (NaOH) and 0.84 wt.% of zinc oxide (ZnO). The fibres were spun into 5% and 15% sulphuric acid (H2SO4) baths containing 10% sodium sulphate (Na2SO4). The highest fibre tenacity obtained was 1.8 cNdtex−1 with elongation of 15% and titre of 1.4 dtex. Average molecular weights and shape of molecular weight distribution curves of the celluloses from the novel wet spun cellulosic fibre and from the commercial viscose fibre were close to each other.
Keywords:Biocelsol  Cellulases  Cellulosic fibres  Directly alkaline soluble cellulose  Dissolving pulp  Enzymatic treatment of cellulose
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