The first one-pot amidation of alkanes and cycloalkanes |
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| Authors: | Irena S. Akhrem,Dzul&rsquo etta V. Avetisyan,Lyudmila Afanas&rsquo eva,Sergei V. Vitt,Pavel V. Petrovskii,Alexander Orlinkov |
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| Affiliation: | A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, GSP-1, 28 Vavilova Street, Russia |
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| Abstract: | ![]()
Alkanes (or cycloalkanes) and CO in the presence of superelectrophilic systems CX4·2AlBr3 (X = Cl, Br) have been applied for the first time as equivalents of acylium salts in one-pot selective syntheses of amides from amines. |
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| Keywords: | Alkanes Cycloalkanes Superelectrophiles Functionalization Amines Amides |
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