Reaction of Acetyl and Benzoyl Chlorides with Pyridines and Pyridine N-Oxides |
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| Authors: | Rybachenko V I Schroeder G Chotii K Yu Lenska B Red'ko A N |
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| Institution: | (1) National Academy of Sciences of Ukraine, ul. R. Lyuksemburg 70, Donetsk, 83114, Ukraine;(2) Faculty of Chemistry, Adam Mickiewicz University, Poland |
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| Abstract: | The rate of formation of N- and O-acetyl and benzoyl salts of pyridines and pyridine N-oxides in acetonitrile and methylene chloride and equilibria therein were studied. The process occurs in one step following the SN2 mechanism with a small degree of bond rupture in the transition state. |
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