Magnetic field effect on indole exciplexes: a comparative study

A comparative magnetic field effect (MFE) study was done on indole exciplexes with various acceptors, anthracene, pyrene, all-s-trans-1,4-diphenylbuta-1,3-diene and 9-cyanophenanthrene. A surprisingly low magnetic field effect was detected for the 9-cyanophenanthrene exciplexes and was correlated with exciplex geometry. The wavelength dependence of magnetic field effect confirms the presence of single charge-transfer complex for all the exciplexes with 1,2-dimethylindole.