Sandwich structure of a ruthenium porphyrin and an amino acid hydrazide for probing molecular chirality by circular dichroism |
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| Authors: | Qing-Feng LiangJuan-Juan Liu Jian Chen |
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| Affiliation: | The Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, China |
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| Abstract: | Owing to the strong Lewis acidity of ruthenium porphyrins, a commercial carbonyl ruthenium porphyrin and an amino acid hydrazide can assemble into a sandwich structure. The nature of such a structure is diagnostic of the absolute configuration of the amino acid by circular dichroism. |
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| Keywords: | Circular Dichroism Absolute configuration Amino acid Porphyrin Sandwich structure |
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