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Crystal Structures of 1,5,9,18,22,26-Hexaaza[11.11]-p-cyclophane Adducts; Two-dimensional Supramolecular Networks
Authors:Teresa Borowiak  Maciej Kubicki  Grzegorz Dutkiewicz  Marek Pietraszkiewicz  Oksana Pietraszkiewicz
Affiliation:(1) Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland;(2) Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warszawa, Poland
Abstract:
Two newly identified supramolecular structures arise from self-assembly of the macrocyclic 1,5,9,18,22,26- hexaaza[11.11]-p-cyclophane salts with o-nitrophenol (C28H50N6)4+·4(C6H4NO2O) (1) and with HCl (C28H52N6)6+·6Cl-·4H2O (2). In both cases two-dimensional supramolecular sheets are formed.
Keywords:hydrogen bonding  macrocyclic amines  molecular recognition  two-dimensional supramolecular frameworks  weak and strong acid adducts of  X-ray diffraction
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