Supportless PdFe nanorods as highly active electrocatalyst for proton exchange membrane fuel cell |
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| Authors: | Wenzhen Li Pradeep Haldar |
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| Affiliation: | 1. Department of Chemical Engineering, Michigan Technological University, Houghton, MI 49931, USA;2. College of Nanoscale Science and Engineering (CNSE), State University of New York (SUNY) at Albany, NY 12206, USA |
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| Abstract: | The PdFe nanorods (PdFe-NRs) with tunable length were synthesized by an organic phase reaction of [Pd(acac)2] and thermal decomposition of [Fe(CO)5] in a mixture of oleyamine and octadecene at 160 °C. They show a better proton exchange membrane fuel cell (PEMFC) performance than commercial Pt/C in working voltage region of 0.80–0.65 V, due to their high intrinsic activity to oxygen reduction reaction (ORR), reduced cell inner resistance, and improved mass transport. |
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