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Double-layer capacitance of waste coffee ground activated carbons in an organic electrolyte
Authors:Thomas E Rufford  Denisa Hulicova-Jurcakova  Erika Fiset  Zhonghua Zhu  Gao Qing Lu
Institution:The University of Queensland, ARC Centre of Excellence for Functional Nanomaterials, School of Engineering and Australian Institute for Bioengineering and Nanotechnology, 4072 Qld, Australia
Abstract:Using ZnCl2 activation we prepared a series of carbon electrodes from waste coffee grounds to study the effect of mesopores on double-layer capacitance in a tetraethyl ammonium tetrafluoroborate/acetonitrile electrolyte. The activated carbon with the largest mesopore volume achieved an energy density of 34 Wh kg?1 at low current loads, and significantly retained an energy density of 16.5 Wh kg?1 and specific capacitance of more than 100 F g?1 at fast charge–discharge rates (20 A g?1). The effect of mesopores on capacitance at fast charge–discharge rates is discussed.
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