| 新型含BPP34C10冠醚双吡啶双齿配体的合成 |
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| 引用本文： | 叶余原,金正能,郭海昌,周其忠,蒋华江.新型含BPP34C10冠醚双吡啶双齿配体的合成[J].浙江大学学报(理学版),2010,37(5):563-567. |
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| 作者姓名： | 叶余原 金正能 郭海昌 周其忠 蒋华江 |
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| 作者单位： | 台州学院,化学系,浙江,临海,317000 |
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| 基金项目： | 国家自然科学基金资助项目，科技部基金资助项目，浙江省自然科学基金资助项目 |
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| 摘 要： | 以Sonogashira偶联反应为关键反应来合成化合物4.设计并且用Suzuki偶联反应为关键反应,合成了新型含BPP34C10冠醚的180°双吡啶双齿配体.该双吡啶双齿配体有两个配位点,有望和铂受体用于自组装成新型的超分子建筑.
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| 关 键 词： | 冠醚 双吡啶 双齿配体 |
Synthesis of novel dipyridine ambidentate incorporating BPP34C10 crown ether |
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| YE Yu-yuan,JIN Zheng-neng,GUO Hai-chang,ZHOU Qi-zhong,JIANG Hua-jiang.Synthesis of novel dipyridine ambidentate incorporating BPP34C10 crown ether[J].Journal of Zhejiang University(Sciences Edition),2010,37(5):563-567. |
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| Authors: | YE Yu-yuan JIN Zheng-neng GUO Hai-chang ZHOU Qi-zhong JIANG Hua-jiang |
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| Institution: | (Department of Chemistry,Taizhou University,Linhai 317000,Zhejiang Province,China) |
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| Abstract: | Sonogashira coupling reaction was used as a key step to synthesize compound 4.It is synthesized that a novel BPP34C10 crown ether based 180° dipryidine ambidentate donor by designing and using Suzuki coupling reaction as a key step.This dipyridine ambidentate ligand had 2 coordinating points,which could be used in self-assembly with Pt acceptor into novel supramolecular structure in future. |
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| Keywords: | crown ether dipyridine ambidentate complex |
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