| 具有Cl…Cl作用的一维链状有机锡化合物四(2，4-二氯苄基)锡的合成、表征和晶体结构 |
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| 引用本文： | 尹汉东,高中军,徐浩龙,李刚,洪敏. 具有Cl…Cl作用的一维链状有机锡化合物四(2，4-二氯苄基)锡的合成、表征和晶体结构[J]. 无机化学学报, 2006, 22(2): 371-374 |
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| 作者姓名： | 尹汉东 高中军 徐浩龙 李刚 洪敏 |
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| 作者单位： | 聊城大学化学化工学院,聊城 252059,聊城大学化学化工学院,聊城 252059,聊城大学化学化工学院,聊城 252059,聊城大学化学化工学院,聊城 252059,聊城大学化学化工学院,聊城 252059 |
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| 基金项目： | 国家自然科学基金(No.20271025),山东省自然科学基金(No.L2003B01)资助课题 |
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| 摘 要： | The tetra(2, 4-dichlorobenzyl)tin was synthesized and characterized by elementary analysis, IR and 1H NMR. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to triclinic, space group P1 with a=1.089 7(3) nm, b=1.050 33(4) nm, c=1.858 5(4) nm, α=96.822(4)°, β=94.477(4)°, γ=94.636(3)°, V=3.001 3(12) nm3, Z=4, Dc=1.679 Mg·m-3, μ(Mo Kα)=1.582 mm-1, S=1.005, F(000)=1 496, R1=0.040 7, wR2=0.076 3. In compound, the tin atom has a distorted tetrahedral coordination configuration. The molecules are packed in one-dimensional chain polymer through a weak interaction between the chlorine atoms from adjacent molecules, respectively. CCDC: 286106.
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| 关 键 词： | 四(2,4-二氯苄基)锡 合成 Cl…Cl作用 晶体结构 |
| 文章编号： | 1001-4861(2006)02-0371-04 |
| 收稿时间： | 2005-08-15 |
| 修稿时间： | 2005-11-17 |
Synthesis, Characterization and Crystal Structure of the Cl...Cl Interaction One-dimensional Chain Organotin Compound Tetra(2, 4-dichlorobenzyl)tin |
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| YIN Han-Dong,GAO Zhong-Jun,XU Hao-Long,LI Gang and HONG Min. Synthesis, Characterization and Crystal Structure of the Cl...Cl Interaction One-dimensional Chain Organotin Compound Tetra(2, 4-dichlorobenzyl)tin[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(2): 371-374 |
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| Authors: | YIN Han-Dong GAO Zhong-Jun XU Hao-Long LI Gang HONG Min |
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| Affiliation: | Department of Chemistry, Liaocheng University, Liaocheng, Shangdong 252059,Department of Chemistry, Liaocheng University, Liaocheng, Shangdong 252059,Department of Chemistry, Liaocheng University, Liaocheng, Shangdong 252059,Department of Chemistry, Liaocheng University, Liaocheng, Shangdong 252059 and Department of Chemistry, Liaocheng University, Liaocheng, Shangdong 252059 |
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| Abstract: | |
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| Keywords: | tetra(2 4-dichlorobenzyl)tin synthesis Cl...Cl interaction crystal structure |
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