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A Novel Approach to Synthesis of α,β-Unsaturated Ketones
引用本文:王兰英 ,胡志彪 ,史真.A Novel Approach to Synthesis of α,β-Unsaturated Ketones[J].中国化学,2002,20(5):514-517.
作者姓名:王兰英  胡志彪  史真
作者单位:WANG,Lan Ying HU,Zhi Biao SHI,ZhenDepartment of Chemistry,Northwest University,Xi'an,Shaanxi 710069,China
基金项目:ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No.2 9872 0 32 )andtheSpecialScienceResearchFoundationofEducationCommitteeofShaanxiProvince (No .98JK12 0 )
摘    要:A new approach to the synthesis of α,β-unsaturated ketones from 1,2,3-trimethyl benzimidazolium salt via the condensation reaction with aldehydes followed by the addition reaction of Grignard reagents with quaternary C=N bond was provided.

关 键 词:α  β-不饱和酮  合成方法  有机合成  1  2  3-三甲基苯并咪唑

A Novel Approach to Synthesis of α, β‐Unsaturated Ketones
WANG,Lan Ying HU,Zhi Biao SHI,Zhen.A Novel Approach to Synthesis of α, β‐Unsaturated Ketones[J].Chinese Journal of Chemistry,2002,20(5):514-517.
Authors:WANG  Lan Ying HU  Zhi Biao SHI  Zhen
Institution:WANG,Lan Ying HU,Zhi Biao SHI,ZhenDepartment of Chemistry,Northwest University,Xi'an,Shaanxi 710069,China
Abstract:A new approach to the synthesis of α, β‐unsaturated ketones from 1,2,3‐trimethyl benzimidazolium salt via the condensation reaction with aldehydes followed by the addition reaction of Grignard reagents with quaternary C=N bond was provided.
Keywords:α  β‐unsaturated ketones  1  2  3‐trimethyl benzimidazolium salt  Grignard reagents  synthesis
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