The 1,4-diaza[2.2.2] Bicyclooctane—hydrogen peroxide complex as a source of anhydrous hydrogen peroxide: the preparation of bis(trialkylsilyl) peroxides |
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| Authors: | Peter G Cookson Alwyn G Davies Nasir Fazal |
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| Institution: | Chemistry Department, University College London, 20 Gordon Street, London WC1H OAJ Great Britain |
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| Abstract: | The hazard and inconvenience of storing and handling concentrated hydrogen peroxide can be avoided by using instead the solid complex which 1,4-diazabicyclo2.2.2] octane forms with hydrogen peroxide, it reacts with trialkylchlorosilanes to give bis(trialkylsilyl) peroxides in good yield. |
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| Keywords: | To whom correspondence should be addressed |
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