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A Simple Hydrothermal Method for the Growth of ZnO Crystals
Authors:Yingzi Peng  Dexuan Huo  Liang Zheng  Zhenghong Qian
Affiliation:1. Department of Physics, School of Science, Hangzhou Dianzi University, Hangzhou 310018 (China);2. State Key Lab of Silicon Materials, Zhejiang University, Hangzhou 310027 (China);3. Department of Materials, College of Materials and Environment Engineering, Hangzhou Dianzi University, Hangzhou 310018 (China);4. College of Electronic Information, Hangzhou Dianzi University, Hangzhou 310018 (China)
Abstract:ZnO microstructures have been grown from zinc chloride (ZnCl2) and ammonia solution at 100 °C for 1 – 24 hours. X‐ray diffraction, scanning electron microscope and field‐emission scanning microscope were utilized to investigate the structural properties and morphology of the ZnO crystals. Structural investigations show that phase‐pure hexagonal structure ZnO has been successfully synthesized, and the hexagonal structure ZnO can be achieved in solutions with an appropriate range of concentrations. Under our experimental conditions, several different morphologies of ZnO structures were obtained, including flower‐like and bar flower‐like. The relationship between the morphology and experimental conditions are discussed.
Keywords:crystal structure  hydrothermal growth  morphology  ZnO crystal
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