Silylene additions to cyclopentadiene and 1,3-cyclohexadiene. Evidence for the addition mechanism |
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| Authors: | Rong-Juh Hwang Robert T. Conlin Peter P. Gaspar |
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| Affiliation: | Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14214 U.S.A. |
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| Abstract: | Additions of SiH2, SiCl2 and Si(CH3)2 to cyclopentadiene and of Si(CH3)2 to 1,3-cyclohexadiene were carried out by copyrolysis of an appropriate disilane and the diene. All observed products are believed due to 1,2-addition of silylenes forming bicyclic vinylsilacyclopropane derivatives which undergo non-concerted rearrangements. |
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