Real time and in situ determination of lead in road sediments using a man-portable laser-induced breakdown spectroscopy analyzer |
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Authors: | J Cuñat |
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Institution: | Department of Analytical Chemistry, University of Malaga, E-29071 Malaga, Spain |
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Abstract: | In situ, real time levels of lead in road sediments have been measured using a man-portable laser-induced breakdown spectroscopy analyzer. The instrument consists of a backpack and a probe housing a Q-switched Nd:YAG laser head delivering 50 mJ per pulse at 1064 nm. Plasma emission was collected and transmitted via fiber optic to a compact cross Czerny-Turner spectrometer equipped with a linear CCD array allocated in the backpack together with a personal computer. The limit of detection (LOD) for lead and the precision measured in the laboratory were 190 μg g−1 (calculated by the 3σ method) and 9% R.S.D. (relative standard deviation), respectively. During the field campaign, averaged Pb concentration in the sediments were ranging from 480 μg g−1 to 660 μg g−1 depending on the inspected area, i.e. the entrance, the central part and the exit of the tunnel. These results were compared with those obtained with flame-atomic absorption spectrometry (flame-AAS). The relative error, expressed as 100(LIBS result − flame AAS result)/(LIBS result)], was approximately 14%. |
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Keywords: | Portable laser-induced breakdown spectrometry instrument Traffic pollution Particulate material Lead in situ screening Surface analysis |
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