The first complexes and cyclodimerisations of methylphosphaalkyne (P[triple bond]CMe) |
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| Authors: | Jones Cameron Schulten Christian Stasch Andreas |
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| Institution: | Centre for Fundamental and Applied Main Group Chemistry, School of Chemistry, Main Building, Cardiff University, Cardiff, UK CF10 3AT. jonesca6@cardiff.ac.uk |
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| Abstract: | The first complexes and cyclodimerisations of methylphosphaalkyne, Ptriple bond]CMe, are reported to arise from its reactions with a range of platinum(0) complexes and W(CO)5(THF)]. A number of differences between the chemistry of this phosphaalkyne and that of its bulkier analogues have been highlighted and explained on steric grounds. |
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