UO22+-polycarboxylate heterometallic complexes: structure,spectra, and photocatalytic properties |
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| Authors: | Qing Lin Guan Xue Gao Jing Liu Wen Juan Wei Yong Heng Xing |
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| Affiliation: | 1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, PR China;2. Center Laboratory, Affiliated Zhongshan Hospital of Dalian University, Dalian, PR China;3. Regenerative Medicine Center, First Affiliated Hospital of Dalian Medical University, Dalian, PR China |
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| Abstract: | [Cu2(UO2)4(suc)4(pac)4] (1), [(Cu(H2O)2)(4,4′-bipy)2][(UO2)2(H2O)2(Hca)2]·3H2O (2), and [(Cu(H2O)2)(UO2)(bta)]·4H2O (3) were synthesized by the reaction of succinic acid and 3-pyridinecarboxylic acid, citric acid and 4,4′-bipyridine, or 1,2,4,5-benzenetetracarboxylic acid ligands with Cu(NO3)2·3H2O and UO2(CH3COO)2·2H2O. The complexes were characterized by IR and UV–vis spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction, and photoluminescence spectroscopy. Photocatalytic activities of the complexes were also investigated. |
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| Keywords: | Heterometallic copper uranyl structure photocatalytic activity |
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