Tetrazolate bridged dinuclear photo-luminescent zinc(II) Schiff base complex prepared via 1,3-dipolar cycloaddition at ambient condition |
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| Authors: | Satavisha Bhattacharya Sumit Roy |
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| Institution: | Department of Chemistry, Jadavpur University, Kolkata, India |
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| Abstract: | A bis(μ-NN′-tetrazolate)-bridged centrosymmetric dinuclear zinc(II) Schiff base complex, Zn2(L)2(PZTZ)2] (HL is a tridentate Schiff base, 2-(2-(dimethylamino)ethyliminomethyl)-6-ethoxyphenol and HPZTZ is 2-pyrazinyltetrazole), has been synthesized via 3 + 2] cycloaddition of 2-cyanopyrazine and sodium azide in the presence of zinc(II) acetate dihydrate and HL. The structure of the complex is confirmed by single-crystal X-ray diffraction analysis. The complex shows fluorescence. |
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| Keywords: | Zinc(II) Schiff base 1 3-dipolar cycloaddition 5-pyrazinyltetrazolate |
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