Crystal structure and spectroscopic behavior of three new tris-oxalatoferrate(III) salts |
| |
Authors: | Oscar E Piro Gustavo A Echeverría Roberto C Mercader Ana C González-Baró |
| |
Institution: | 1. Facultad de Ciencias Exactas, Departamento de Física, Instituto Física de La Plata (IFLP, CONICET, CCT-La Plata), Universidad Nacional de La Plata, La Plata, Argentina;2. Facultad de Ciencias Exactas, Centro de Química Inorgánica (CEQUINOR, CONICET/UNLP), Universidad Nacional de La Plata, La Plata, Argentina |
| |
Abstract: | A new general synthetic procedure for preparation of Na3Fe(C2O4)3]·5H2O (1), Rb3Fe(C2O4)3]·3H2O (2), and Cs3Fe(C2O4)3]·2H2O (3) was developed. The crystal structures of these salts have been determined by single crystal X-ray diffraction. Salt 1 crystallizes in the monoclinic space group C2/c with Z = 8, salt 2 in P21/c with Z = 4, and salt 3 in P21/n with Z = 4. The three new salts and K3Fe(C2O4)3]·3H2O, prepared for comparative purposes, were further characterized by infrared and 57Fe-Mössbauer spectroscopy. These spectra are discussed in comparison with those of related oxalato complexes. |
| |
Keywords: | Tris-oxalatoferrate(III) alkaline salts crystal structures infrared spectra 57Fe-Mössbauer spectra |
|
|