| 由水杨醇衍生的二苯并冠醚的合成和构型 |
| |
| 引用本文： | 黄枢,孟杰.由水杨醇衍生的二苯并冠醚的合成和构型[J].高等学校化学学报,1995,16(11):1744-1746. |
| |
| 作者姓名： | 黄枢 孟杰 |
| |
| 作者单位： | 四川大学化学系 |
| |
| 摘 要： | 将水杨醇在ＤＭＦ中与ＮａＨ和二甘醇或三某醇二对甲苯磺酸酯反，合成了２个新的二苯并冠醚（１和２），其结构由元素分析和波谱分析所表征，１ 射线衍射分析确定为反位构型，提出了合成反应的机理。
|
| 关 键 词： | 二苯并冠醚 水杨醇 构型 |
Syntheis and configuration of Dibenzo-Crown Ethers Derived from Salicyl Alcohol |
| |
| HUANG Shu,MENG Jie,MAO Zhi-Hua,TIAN Bao-Zhi.Syntheis and configuration of Dibenzo-Crown Ethers Derived from Salicyl Alcohol[J].Chemical Research In Chinese Universities,1995,16(11):1744-1746. |
| |
| Authors: | HUANG Shu MENG Jie MAO Zhi-Hua TIAN Bao-Zhi |
| |
| Abstract: | Two dibenzocrown ethers(1 and2) were synthesized by the reaction of salicyl alcohol with NaH and di-and triethyleneglycol ditosylates in DMF, Their structures were characterized by elemental analysis, IR,1HNMR and MS. Dibenzo-20-crown ether(1)was confirmed as anti-configuration by the X-ray diffraction analysis of its single crystal.According to the configuration of 1, the reaction mechanism of the synthesis is proposed. |
| |
| Keywords: | Dibenzocrown ether Macrocyclic compound Salicyl alcohol Configuration |
| 本文献已被 CNKI 维普 等数据库收录！ |
