Photochemical reactivity of α,β-unsaturated δ-lactams: Synthesis of seco-steroids. Photochemical reactions. XIII [1] |
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| Authors: | Antonio C novas,Jesú s Fonrodona,Juan-Julio Bonet,Marie Claire Brians ,Jos Luis Brians |
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| Affiliation: | Antonio Cánovas,Jesús Fonrodona,Juan-Julio Bonet,Marie Claire Briansó,José Luis Briansó |
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| Abstract: | ![]()
The UV. irradiation of 17 β-hydroxy-2-aza-4-androsten-3-one (1) , N-methyl-17 β-hydroxy-2-aza-4-androsten-3-one (3) , 17 β-hydroxy-4-aza-5 β-androst-1-en-3-one (2) and N-methyl-17 β-hydroxy-4-aza-5 β-androst-1-en-3-one (4) , gives rise to 1,10-seco (from 1 and 3 ) and 5, 10-seco (from 2 and 4 ) steroids. |
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