Evaluation of a carbon paste electrode modified with organofunctionalized amorphous silica in the cadmium determination in a differential pulse anodic stripping voltammetric procedure

The determination of cadmium using a carbon paste electrode modified with organofunctionalized amorphous silica with 2-benzothiazolethiol was investigated. The Cd(II) oxidation peak was observed around −0.80 V (vs. SCE) in phosphate buffer (pH 4.0) in differential pulse anodic stripping voltammetry. The best results were obtained under the following optimized conditions: 1 min accumulation time, 50 mV pulse amplitude, 20 mV s⁻¹ scan rate in phosphate buffer pH 4.0. Using such parameters a linear dynamic range from 5.6×10⁻⁷ to 3.5×10⁻⁵ mol l⁻¹ Cd(II) was observed with a sensitivity of 2.83 μA mol⁻¹ l, limit of detection 1.0×10⁻⁷ mol l⁻¹. Cd(II) spiked in a natural water sample was determined with 99% mean recovery at 10⁻⁷ mol l⁻¹ level. Interference were also evaluated.