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Formation of carbamates by reaction between ester carbanions and isocyanates: General regularities and scope |
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| Authors: | Yuri G. Gololobov Yuri A. Borisov Nikolii Slepchenkov Sergey Barabanov Pavel V. Petrovskii Julija V. Nelyubina |
| Abstract: | General regularities and scope of reactions carbanions with the ester group at carbanionic center and arylisocyanates resulting formation of carbamates by C → N migrations of ester groups have been described. The use of tosylisocyanates terminated reactions at the first stage with formation of corresponding tosylacylamides. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:119–125, 2010; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20585 |
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