Synthesis of new organophosphorus‐substituted mono‐ and bis(trimethylsilyl)amines with PCH2N fragments and their derivatives

Convenient procedures for the synthesis of new organophosphorus‐substituted mono‐ and bis(trimethylsilyl)amines with PCH₂N moiety are proposed, starting from trimethylsilyl esters of organophosphorus acids, as well as 1,3,5‐trialkylhexahydro‐1,3,5‐triazines and N‐alkoxymethyl bis(trimethylsilyl)amines as aminomethylating reagents. Certain properties of the resulting compounds are presented. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:71–77, 2010; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20580