Controlled cyclopolymerization through quantitative 19-membered ring formation |
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| Authors: | Ochiai Bungo Ootani Yuuko Endo Takeshi |
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| Affiliation: | Department of Polymer Science and Engineering, Faculty of Engineering, Yamagata University, Jonan 4-3-16, Yonezawa, Yamagata, Japan. |
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| Abstract: | ![]()
Cyclopolymerization of a bis-methacrylate monomer derived from trans-cyclohexanediol and 2-methacryloyloxyethyl isocyanate proceeded through 19-membered ring formation. The unusual large ring formation originated from the designed steric regulation by the cyclohexane ring and the hydrogen bonds. The RAFT polymerization employing cumyl dithiobenzoate attained controlled polymerization, which supported the quantitative cyclization. |
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