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电荷转移金属[60]富勒烯盐的光电性质
引用本文:刘秀,郭立俊,王文军,姜永强,王恭明.电荷转移金属[60]富勒烯盐的光电性质[J].光学学报,2002,22(2):23-225.
作者姓名:刘秀  郭立俊  王文军  姜永强  王恭明
作者单位:复旦大学光科学与工程系,上海,200433
基金项目:国家自然科学基金 (19834 0 30、6 96 870 0 4),上海市应用物理中心资助课题
摘    要:用物理喷束淀积技术制备了过渡金属60]富勒烯盐C60Ni薄膜,研究了Al/C60Ni/ITO光电池的光伏效应和正反向电学特性并与Al/C60/ITO膜进行了比较。用界面偶极电场解释了Al/C60Ni界面光伏效应和整流应的增强,表明在该样品中发生的从Ni原子到C60的电子转移使Al/C60Ni界面偶极电场增强。

关 键 词:金属[60]富勒烯盐  光伏效应  界面偶极电场  光电性质  电子转移  碳60  C60  整流效应  固态膜

Photoelectric Characteristics of Charge Transferring Metal Doped [60] Fullerenes
Liu Xiu,Guo Lijun,Wang Wenjun,Jiang Yongqiang,Wang Gongming.Photoelectric Characteristics of Charge Transferring Metal Doped [60] Fullerenes[J].Acta Optica Sinica,2002,22(2):23-225.
Authors:Liu Xiu  Guo Lijun  Wang Wenjun  Jiang Yongqiang  Wang Gongming
Abstract:Physical jet deposition (PJD) method was used to form the C 60Ni films, one of the transition metal fullerides films, which were made into the Al/C 60Ni/ITO(indium tin oxide) layered structure photovoltaic cells. The photovoltaic effect and the forward and backward current-voltage characteristic of the cells were investigated and compared with the Al/C 60/ITO films. The enhancement of photovoltaic effect and rectification of Al/C 60Ni interface was observed. It indicates the buildup of interface electrical dipolar field on the Al/C 60Ni interface, which was caused by the charge transfer from Ni atoms to C 60 molecules in the samples.
Keywords:metal doped fullerenes  photovoltaic effect  interface electrical dipolar field
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