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Muon-oxygen bonding in V2O3
Authors:K. C. B. Chan  R. L. Lichti  C. Boekema  A. B. Denison  D. W. Cooke  M. E. Schillaci
Affiliation:(1) Department of Physics, Texas Tech University, 79409 Lubbock, TX, USA;(2) Physics Department, San José State University, 95192 San José, CA, USA;(3) Physics Department, University of Wyoming, 82701 Laramie, WY, USA;(4) Los Alamos National Laboratory, 87545 Los Alamos, NM, USA
Abstract:
A muon site search using calculated internal fields has been performed for V2O3, where purely dipolar fields allow a site determination free from covalent complications. The obtained sites are a subset of the Rodriguez and Bates sites found in α-Fe2O3 and indicate muon oxygen bond formation. The sites missing at low temperatures are consistent with the vanadium pairing mechanism for the metal-to-insulator (corundum-to-monoclinic) phase transition.
Keywords:
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