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| 三种二元水溶液体系中氢键对拉曼线宽的影响 | |
| 引用本文： | 吴楠楠,张雪峰,欧阳顺利,韩向刚.三种二元水溶液体系中氢键对拉曼线宽的影响[J].光谱学与光谱分析,2012,32(11):3031-3034. |
| 作者姓名： | 吴楠楠 张雪峰 欧阳顺利 韩向刚 |
| 作者单位： | 1. 内蒙古科技大学内蒙古自治区白云鄂博矿多金属资源综合利用重点实验室(省部共建国家重点实验室培育基地)，内蒙古 包头 014010 2. 内蒙古科技大学稀土学院，内蒙古 包头 014010 3. 内蒙古科技大学数理与生物工程学院，内蒙古 包头 014010 |
| 基金项目： | 国家重点基础研究发展计划(973计划)前期专项项目，国家自然科学基金项目，内蒙古自治区创新团队冶金与资源利用项目 |
| 摘 要： | 采用显微共聚焦拉曼光谱对三种二元水溶液(乙腈/水、二甲基亚砜(DMSO)/水和丙酮/水)进行测量，得到含有氢键作用的水溶液体系拉曼频移和线宽随浓度的变化规律。应用混合模型和相互作用体系的线宽经验公式对实验结果进行了分析。结果表明，含有氢键作用的水溶液体系中，氢键作用越强线宽越大,并且线宽随单位浓度变化率大;同种氢键体系中，线宽不仅受浓度浮动的影响，氢键作用也是一个重要的影响因素，定量分析证明线宽与浓度、氢键作用关系很好地符合Ojha等提出的线宽公式。 |
| 关 键 词： | 氢键 线宽 拉曼光谱 水溶液 |
| 收稿时间： | 2012-04-19 |
Effect of Hydrogen Bond on Line Width of Raman Spectra in Three Aqueous Solutions |
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| WU Nan-nan , ZHANG Xue-feng , OUYANG Shun-li , HAN Xiang-gang.Effect of Hydrogen Bond on Line Width of Raman Spectra in Three Aqueous Solutions[J].Spectroscopy and Spectral Analysis,2012,32(11):3031-3034. | |
| Authors: | WU Nan-nan ZHANG Xue-feng OUYANG Shun-li HAN Xiang-gang |
| Institution: | 1. Inner Mongolia Key Laboratory for Utilization of Baiyunebo Multi-Metallic Resources (Elected State Key Laboratory), Inner Mongolia University of Science and Technology, Baotou 014010, China2. School of Rare Earth, Inner Mongolia University of Science and Technology, Baotou 014010, China3. School of Mathematics, Physics and Biological Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China |
| Abstract: | In the present paper, the frequency shift and line widths of acetonitrile/H2O, DMSO/H2O and acetone/H2O aqueous binary solutions at different concentration were measured by Raman spectroscopy. The experimental results were analyzed by mixture model and empirical formula of line widths. The results show that the stronger the hydrogen bond interaction, the greater the line widths of Raman spectra in the three aqueous binary solutions; the line width of Raman spectra not only is affected by concentration fluctuation, but also is affected by hydrogen bond. In addition, the experimental data points are again nicely fitted using the empirical formula. |
| Keywords: | Hydrogen bond Line width Raman spectra Aqueous solution |
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