| 杂金属杯[4]配位聚合物的合成与表征 |
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| 引用本文： | 张夏,薛军儒,何站,张淑芳,梁月,秦大斌,敬林海. 杂金属杯[4]配位聚合物的合成与表征[J]. 无机化学学报, 2013, 29(18) |
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| 作者姓名： | 张夏 薛军儒 何站 张淑芳 梁月 秦大斌 敬林海 |
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| 作者单位： | 四川省化学合成与环境控制重点实验室, 西华师范大学化学化工学院, 南充 637002,四川省化学合成与环境控制重点实验室, 西华师范大学化学化工学院, 南充 637002,四川省化学合成与环境控制重点实验室, 西华师范大学化学化工学院, 南充 637002,四川省化学合成与环境控制重点实验室, 西华师范大学化学化工学院, 南充 637002,四川省化学合成与环境控制重点实验室, 西华师范大学化学化工学院, 南充 637002,四川省化学合成与环境控制重点实验室, 西华师范大学化学化工学院, 南充 637002,四川省化学合成与环境控制重点实验室, 西华师范大学化学化工学院, 南充 637002 |
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| 基金项目： | 国家自然科学基金（No.21671159）和四川省合成与污染控制重点实验室基金（No.CSPC2014-4-1）资助项目。 |
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| 摘 要： | 合成了4个杂金属杯[4]配位聚合物{[Cd（L）（tpa）]·3H2O}n（1）,{[Zn2（L）2（tpa）2]·3H2O}n（2）,{[Co（L）（oba）]·2DMA·0.5H2O}n（3）和{[Zn（L）（oba）]·DMA}n（4）（L=2-（1H-咪唑基-甲基）-6-（3-（1H-咪唑基-甲基）-5-叔丁基-2-羟基）苄基-4-叔丁基苯酚,H2tpa=对苯二甲酸,H2oba=4,4''-二苯醚二甲酸）,并通过元素分析、热重、红外光谱、固态紫外、单晶X射线衍射和粉末X射线衍射对其进行了表征。单晶结构分析表明晶体1是单斜晶系,P21/n空间群,而晶体2,3和4均为三斜晶系,P1空间群。化合物1,2,3和4是由0维[M（N4O2C29H36）]（M=Zn,Co,Cd）的杂金属杯[4]与配体对苯二甲酸和4,4''-二苯醚二甲酸形成的一维配位聚合物。
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| 关 键 词： | 金属杯芳烃 配位聚合物 水热合成 |
| 收稿时间： | 2016-10-15 |
| 修稿时间： | 2017-01-14 |
Syntheses and Characterization of Metal Hybrid Calix[4]arene Coordination Polymers |
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| ZHANG Xi,XUE Jun-Ru,HE Zhan,ZHANG Shu-Fang,LIANG Yue,QIN Da-Bin and JING Lin-Hai. Syntheses and Characterization of Metal Hybrid Calix[4]arene Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(18) |
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| Authors: | ZHANG Xi XUE Jun-Ru HE Zhan ZHANG Shu-Fang LIANG Yue QIN Da-Bin JING Lin-Hai |
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| Affiliation: | Key Laboratory of Chemical Synthesis and Pollution of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China,Key Laboratory of Chemical Synthesis and Pollution of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China,Key Laboratory of Chemical Synthesis and Pollution of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China,Key Laboratory of Chemical Synthesis and Pollution of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China,Key Laboratory of Chemical Synthesis and Pollution of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China,Key Laboratory of Chemical Synthesis and Pollution of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China and Key Laboratory of Chemical Synthesis and Pollution of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong, Sichuan 637002, China |
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| Abstract: | Four metal hybrid calix[4]arene coordination polymers:{[Cd(L)(tpa)]·3H2O}n (1), {[Zn2(L)2(tpa)2]·3H2O}n (2), {[Co(L)(oba)]·2DMA·0.5H2O}n (3) and {[Zn(L)(oba)]·DMA}n (4) (L=2-((1H-imidazol-1-yl)methyl)-6-(3-((1H-imidazol-1-yl)methyl)-5-tert-butyl-2-hydroxybenzyl)-4-tert-butylphenol, H2tpa=terephthalic acid, H2oba=4,4''-oxy-bisbenzoic acid) have been successfully synthesized and characterized by elemental analysis, thermogravimetry, IR, the solid-sate UV-Vis spectra, single-crystal X-ray diffraction and PXRD. The single-crystal X-ray diffraction analysis reveals that complex 1 crystallizes in the monoclinic system, space group P21/n while complexes 2, 3 and 4 crystallize in the triclinic, space group P1. Complexes 1, 2, 3 and 4 are one-dimensional coordination polymers, which are formed through 0D[M(N4O2C29H36)] (M=Zn, Co, Cd) metal hybrid calix[4]arene bridged H2tpa and H2oba ligands. |
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| Keywords: | metal calixarene coordination polymers hydrothermal synthesis |
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