Analysis of correlation patterns in hyperfine sublevel correlation spectroscopy of<Emphasis Type="Italic">S</Emphasis>=1/2,<Emphasis Type="Italic">I</Emphasis>=3/2 systems |
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Authors: | M Gutjahr R Böttcher A Pöppl |
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Institution: | 1.Fakult?t für Physik und Geowissenschaften,Universit?t Leipzig,Leipzig,Germany |
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Abstract: | The properties of two-dimensional four-pulse electron spin echo envelope modulation spectra of nuclei with nuclear spinI=3/2 in disordered systems are discussed by means of calculated lithium hyperfine sublevel correlation spectra. Since a case of small coupling is treated, the multifrequency transition components appear only in the first quadrant of the two-dimensional spectra. The influence of the hyperfine and nuclear quadrupole interaction parameters on the cross peak ridges in the two-dimensional powder pattern is analyzed. Furthermore the possibility to determine the magnitude of the dipolar hyperfine and the nuclear quadrupole coupling from the cross peak line shapes is investigated. In this context the potential of those spectral features representing the so-called multiquantum transitions for the interpretation of the spectra is demonstrated. |
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