| 二元酚类化合物的流动注射化学发光抑制分析法 |
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| 引用本文： | 崔华 孟荣. 二元酚类化合物的流动注射化学发光抑制分析法[J]. 发光学报, 1999, 20(2): 158-164 |
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| 作者姓名： | 崔华 孟荣 |
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| 作者单位： | 中国科学技术大学化学系 |
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| 基金项目： | 中国科学技术大学青年科学基金 |
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| 摘 要： | 发现邻苯二酚，对频丁基邻苯地酚，对苯二酚，３，４－二羟基苯甲对Ｃｏ＾２＋催化的鲁米诺－过氧化化学发光反应有较强的抑制作用，在此基础上建立了四种二元酚类化合物的流动 射化学发光抑制分析法。
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| 关 键 词： | 邻苯二酚 二元酚 分析 流动注射 化学发光 |
FLOW INJECTION ANALYSIS OF POLYPHENOLS WITH INHIBITED CHEMILUMINESCENCE DETECTION |
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| Cui Hua Meng Rong Jiang Haiyan Zhao Huazhang. FLOW INJECTION ANALYSIS OF POLYPHENOLS WITH INHIBITED CHEMILUMINESCENCE DETECTION[J]. Chinese Journal of Luminescence, 1999, 20(2): 158-164 |
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| Authors: | Cui Hua Meng Rong Jiang Haiyan Zhao Huazhang |
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| Abstract: | It was found that catechol, p t butylpyrocatechol, hydroquinone and protocatechuic acid inhibited chemiluminescence from luminol H 2O 2 Co 2+ reaction. On this basis, a flow injection procedure combined with inhibited chemiluminescence detection was developed for the determination of these compounds. The method is fast, simple and sensitive. These polyphenols were detectable at picomolar levels. Furthermore, the mechanism of chemiluminescence inhibition by polyphenols was proposed to be due to the reaction between polyphenol and radical intermediates of chemiluminescent reaction. |
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| Keywords: | catechol p t butylpyrocatechol hydroquinone protocatechuic acid inhibited chemiluminescence flow injection analysis |
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