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醋酸H2O精馏中萃取剂的计算机辅助筛选
引用本文:唐聪明,李新利.醋酸H2O精馏中萃取剂的计算机辅助筛选[J].应用化学,2006,23(9):1066-0.
作者姓名:唐聪明  李新利
作者单位:西华师范大学化学化工学院
摘    要:醋酸H2O精馏中萃取剂的计算机辅助筛选;Flash;萃取剂筛选;萃取精馏;醋酸

关 键 词:醋酸H2O精馏中萃取剂的计算机辅助筛选  Flash  萃取剂筛选  萃取精馏  醋酸  
文章编号:1000-0518(2006)09-1066-03
收稿时间:10 3 2005 12:00AM
修稿时间:03 17 2006 12:00AM

Computer-assisted Choice of Extractive Solvent in the Distillation of Acetic-H2O
TANG Cong-Ming,LI Xin-Li.Computer-assisted Choice of Extractive Solvent in the Distillation of Acetic-H2O[J].Chinese Journal of Applied Chemistry,2006,23(9):1066-0.
Authors:TANG Cong-Ming  LI Xin-Li
Institution:School of Chemistry And Chemical Engineering, China West Normal University ,Nanchong 637002
Abstract:In order to find out effective solvents in extractive distillation,relative volatilities were calculated by means of the Flash unit in Aspen Plus 10.2 simulator.Two Flash operational types and some different thermodynamic models in phase equilibrium were considered respectively.For an acetic acid-water system,the relative volatility of water to acetic acid was given by this method.N-methylacetamide and sulfolane were selected as(effective) solvents,which have relatively high volatility values.Furthermore,VLE phase diagrams for acetic acid-water-solvent systems were obtained to observe the effect in the whole range of concentration.A binary system of N,N-dimethyl formamide-acetic acid was also calculated,showing the formation of a binary azeotrope.
Keywords:flash  solvent selection  extractive distillation  acetic acid
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