| Hydrothermal Synthesis and Characterization of a One—Dimen—sional Copper（Ⅰ） Halide Cluster with 1,10—Phenanthroline |
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| 引用本文： | 于杰辉,施展,等.Hydrothermal Synthesis and Characterization of a One—Dimen—sional Copper（Ⅰ） Halide Cluster with 1,10—Phenanthroline[J].中国化学,2002,20(6):560-563. |
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| 作者姓名： | 于杰辉 施展 |
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| 作者单位： | [1]CollegeofChemistryandStateKeyLaboratoryofInorganicSynthesisandPreparativeChemistry,JilinUniversity,Changchun,Jilin130023,China [2]CollegeofChemistryandStateKeyLaboratoryofInorganicSynthesisandPreparative,JilinUniversity,Changchun,Jilin130023,China |
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| 摘 要： |
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| 关 键 词： | 氯化铜 铜配合物 水热合成 结构 1 10－菲咯啉 |
Hydrothermal Synthesis and Characterization of a One‐Dimensional Copper (I) Halide Cluster with 1,10‐Phenanthroline |
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| Jie‐Hui Yu,Zhan Shi,Ji‐Qing Xu,Xiao‐Bing Cui,Hong Ding,Wei‐Jie Jing,De‐Qing Chu,Jia Hua,Jia‐Ning Xu,Tie‐Gang Wang.Hydrothermal Synthesis and Characterization of a One‐Dimensional Copper (I) Halide Cluster with 1,10‐Phenanthroline[J].Chinese Journal of Chemistry,2002,20(6):560-563. |
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| Authors: | Jie‐Hui Yu Zhan Shi Ji‐Qing Xu Xiao‐Bing Cui Hong Ding Wei‐Jie Jing De‐Qing Chu Jia Hua Jia‐Ning Xu Tie‐Gang Wang |
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| Abstract: | The title compound Cu2Cl2phen (phen = 1,10‐phenanthroline, C12H8N2) 1 was synthesized from CuCl2·2H2O, CuCl and phen by hydrothermal method and its structure was determined by single crystal X‐ray analysis. With phen, CuG forms one‐dimensional chains, which comprise two zigzag chains based on fused Cu‐X units and connected via covalent bonds. The compound contains two crystallographically unique monovalent copper ions, Cu(1) and Cu(2). The Cu(1) atom in the tetrahedral site, is coordinated to two bridging Cl? and two N atoms in phen. The Cu(2) atom with a slightly distorted triangular planar geometry, is coordinated to three Cl?. The compound 1 was crystallized in monoclinic, space group P21/n with a = 0.37338(4), b = 1.9510(2), c = 1.68008(19) nm, β = 95.605 (3)°, R = 0.0458, and was characterized by elemental analysis, IR spectrum and TGA analysis. |
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| Keywords: | hydrothermal synthesis crystal structure copper(I) halide 1 10‐phenanthroline |
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